Q1iii / 19B11: Constituents of plasma + function of albumin

19B11: Exam Report

Outline the composition of plasma (50% of marks). Describe the functions of albumin (50% of marks).

30% of candidates passed this question.

A good answer began with a definition of plasma and then listed the components – water, albumin, globulins, fibrinogen and other proteins before mentioning the lipid content, nutrient content, wastes and electrolytes. Frequently the breakdown of the globulin component was inaccurate. A common omission was dissolved gas components. Descriptions of the calculation of oncotic pressure and GFR were not asked and hence did not attract marks.

The functions of albumin may be subdivided into: Osmotic pressure, transport function, acid-base buffer, anti-oxidant, anticoagulant effect, protein store, metabolism and ‘other’.

Q1iii / 19B11: Outline the composition of plasma (50 marks). Describe the functions of albumin (50 marks)

Definition & Normal Values

  • Plasma = the fluid medium of the intravascular compartment which transports substances between tissues
  • Plasma ≈ 40mL/kg

NB: Serum = whole blood which has settled & clot removed

i.e. Plasma – (clotting factors + fibrinogen)

Plasma Components

  • Water → 94% of plasma is H2O
  • Electrolytes
  • Dissolved Gases (N2, CO2, O2)
  • Waste
  • Plasma carbohydrates → mainly glucose
  • Plasma lipids → mainly paired with plasma proteins
  • Plasma proteins:

Plasma Protein

Type

Albumin

Amt (g/L)

45

Role

See below

Type

Globulins

α1

Amt (g/L)

25

Role

α-1 antitrypsin – protease inhibitor, inhibits trypsin, chymotrypsin, plasma

Lipoproteins – chylomicrons, VLDL, LDL, HDL → transport lipids

α1 acid glycoprotein – binding basic drugs, acute phase reactant

Type

α2

Amt (g/L)

25

Role

α2 macroglobulin – protease inhibitor

Prothrombin – coagulation

Haptoglobin – scavenges free Hb (intravascular haemolysis)

Caeruloplasmin – binds copper, acute phase reactant

Type

β

Amt (g/L)

25

Role

Transferrin – binds 2Fe3+

Type

γ

Amt (g/L)

25

Role

Immunoglobulins → from B lymphocytes

IgG

76%

Binds complement

IgA

16%

Present in seromucous secretions

IgM

7%

Fixes complement

IgE

1%

Binds MCs in hypersensitivity

Type

Fibrinogen

Amt (g/L)

3

Role

Final step of coagulation → fibrin clot

Type

Cytokine

Amt (g/L)

Role

IL, IFN, chemokines, lymphokines, TNF → mediate immune response

Type

Complement

Amt (g/L)

Role

25 proteins produced by liver/RES → innate immunity amplification

Type

CRP

Amt (g/L)

Role

Inflammatory mediator

Type

Coagulation

Amt (g/L)

Role

Trigger coagulation cascade – biological amplification system

Role of Albumin

Endogenous albumin is produced exclusively by hepatocytes, 9-12g/day.

Osmotic Pressure

  • NFP = k[(Pc – Pi) – σ (πc – πi)]
  • Capillaries are impermeable to plasma proteins
  • ∴exert oncotic P ~25mmHg, holds fluid intravascularly
  • Confers 80% of osmotic pressure

Transport

  • Binds acidic, basic and neutral drugs
  • Domains I and II are responsible for transport of numerous endogenous & exogenous molecules; eg unconjucgated bilirubin, thyroid hormone

Acid-Base Buffer

  • 16 Imidazole residues w pK 6.75
  • Buffer extracellular pH

Anti-Oxidant

  • Neutralizes by-products of metabolism which would otherwise be converted to free radicals
  • Conferred by the cysteine residues in position 34 which expose a -SH radical group (thiol) = one of the main extracellular antioxidants

Anticoagulant

  • Enhances AT III activity

Protein Store

  • 50% of plasma protein
  • Often used as a nutritional marker

Metabolism

  • Protein broken down → amino acid → E
  • Drug Metabolism

Other

  • Inflammatory marker